Equilibrium spreading pressure of the mixed system of normal long chain fatty acids.
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概要
- 論文の詳細を見る
Equilibrium spreading pressure were measured at various compositions and temperatures for mixed systems of tridecanoic acid-myristic acid, myristic acid-pentadecanoic acid, and pentadecanoic acid-palmitic acid, and thermodynamical treatment of these data with respect to the equilibrium between crystal and monolayer was performed. By evaluating the equilibrium composition of monolayer phase from the measured curve of equilibrium spreading pressure <I>vs</I>. composition of solid phase, the phase diagram was constructed. It was found that the equilibrium curve has a maximum point where the solid and monolayer phases have the same composition and a point where the solid phase is in equilibrium with two monolayer phases. The partial molar enthalpy change accompanied by the phase transition from solid to monolayer were found to be dependent on the composition.
- 公益社団法人 日本化学会の論文
著者
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FUJII Kozo
Department of Cardiovascular Medicine, Yamaguchi University Graduate School of Medicine
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Nakamura Makoto
Department Of Applied Chemistry Faculty Of Systems Engineering Wakayama University
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Motomura Kinsi
Department Of Chemistry Faculty Of Science Kyushu University
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Matuura Ryohei
Department of Chemistry Faculty of Science Kyushu University
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Yoshino Seiji
Department of Chemistry, Faculty of Science, Kyushu University
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Fujii Kozo
Department of Chemistry, Faculty of Science, Kyushu University
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