Direct Synthesis of Trimethoxysilane from Methanol and Hydrogen-Treated Silicon Using Copper(II) Chloride as a Catalyst.
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概要
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When silicon, on which copper(II) chloride was supported, was pretreated under a hydrogen stream at 533 K and brought in contact with methanol at 533 K, trimethoxysilane was formed with an 89% selectivity and a complete silicon conversion in 5.5 h. Pits were formed on the silicon surface, and grew with increasing silicon conversion.
- 公益社団法人 日本化学会の論文
著者
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ONO Yoshio
Department of Chemistry and Materials Science, Graduate School of Science and Engineering, Tokyo Ins
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Suzuki Eiichi
Department Of Applied Chemistry Tokyo Institute Of Technology
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Kamata Takatsugu
Department of Chemical Engineering, Tokyo Institute of Technology
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