Reaction of 1,2-dichloroethane with pyridine using the 1R,4S,8R,11S-tetramethyl-1,4,8,11-tetraazacyclotetra-decaneickel(II) cation as a probe.
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概要
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A spectral change of the title square planar cation [Ni(tmc)]<SUP>2+</SUP> by an axial ligation of the halide ions in nitrobenzene was applied to kinetic studies of pyridine and alkyl halides. The ligation of the chloride ions proceeds with a formation constant of more than 1×10<SUP>4</SUP> dm<SUP>3</SUP> mol<SUP>−1</SUP> and rapidly with a rate of less than millisecond. It was found that 1,2-dichloroethane and dichloromethane react with pyridine through the Menschutkin reaction with a rate constant of 1.2×10<SUP>−8</SUP> and 3.7×10<SUP>−9</SUP> dm<SUP>3</SUP> mol<SUP>−1</SUP> s<SUP>−1</SUP> at 35°C, respectively.
- 公益社団法人 日本化学会の論文
著者
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Yokoyama Takashi
Department Of Chemistry Faculty Of Science Kyushu University
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NISHIMOTO Jun
Department of Chemistry, Faculty of Science and Engineering, Saga University
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Kumamaru Takahiro
Department Of Chemistry Faculty Of Science Hiroshima University
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Iwamoto Etsuro
Department of Chemistry, Faculty of Science, Hiroshima University
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Kumamaru Takahiro
Department of Chemistry, Faculty of Sciences, Hiroshima University
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Yamashita Tamao
Department of Chemistry, Faculty of Sciences, Hiroshima University
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