Formation of Ketenimines by the Reaction of Thioamides with Diethyl Azodicarboxylate and Triphenylphosphine
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概要
- 論文の詳細を見る
The reaction of diphenylacetothioanilide with diethyl azodicarboxylate and triphenylphosphine gave rise to the formation of diphenylketene(<I>N</I>-phenyl)imine. Similarly, the reaction of <I>N</I>-(<I>p</I>-tolyl)diphenylacetothioamide gave diphenylketene(<I>N</I>-<I>p</I>-tolyl)imine. On treatment with diethyl azodicarboxylate in the presence of sodium ethoxide, diphenylacetothioanilide afforded bis(<I>N</I>-phenylbenzalimidoyl) disulfide in a good yield. The intermediate of the formation of the ketenimines is also discussed.
- 公益社団法人 日本化学会の論文
著者
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Wada Makoto
Department Of Chemistry Faculty Of Integrated Arts And Sciences The University Of Tokushima
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Mitsunobu Oyo
Department Of Chemistry College Of Science And Engineering Aoyama Gakuin University
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Kato Koki
Department of Chemistry, College of Science and Engineering, Aoyama Gakuin University
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