The Alkylation of 3,5-Dimethylisoxazole

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概要

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• 3,5-Dimethylisoxazole (<B>1</B>) was alkylated with sodium amide in liquid ammonia to give 3-methyl-5-alkylisoxazoles. By di- and tri-alkylation reactions using excess sodium amide, isoxazoles having secondary and tertiary alkyl groups at 5-position could be obtained. The hydrogenolysis and hydrolysis of these isoxazoles were also studied.

• 公益社団法人 日本化学会の論文

著者

• Yamamoto Makoto

  Department Of Bacteriology National Institute Of Health

• Sugiyama Noboru

  Department of Chemistry Faculty of Science Tokyo University of Education

• Kashima Choji

  Department of Chemistry, The University of Tsukuba

• Tobe Shinji

  Department of Chemistry, Tokyo Kyoiku University

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