Proton Magnetic Resonance of Metal Ammine Complexes. IV. Paramagnetic Anisotropy of Cobalt(III) Ions as Exemplified in Proton Chemical Shifts
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概要
- 論文の詳細を見る
A theory is presented which couples the proton chemical shift induced by the paramagnetic anisotropy with the chemical shift of the central cobalt-59 nucleus. The theory has been successfully applied to twenty cobalt-(III) α-aminocarboxylate complexes. It is shown that it can be used not only to assign proton NMR signals but also to determine the structure of the complex and, in certain cases, the conformation of ligand molecules.
- 公益社団法人 日本化学会の論文
著者
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YONEDA Hayami
Department of Chemistry, Faculty of Science, Hiroshima University
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Nakashima Yoshiaki
Department Of Surgery Ii Nagoya City University Medical School
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Sakaguchi Ushio
Department of Chemistry, Faculty of Science, Hiroshima University
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Nakashima Yoshiaki
Department of Chemistry, Faculty of Science, Hiroshima University
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