Absolute configurations assigned to some octahedral cis-bis(diamine)cobalt(III) complexes on the basis of their stereoselective interactions in solution.
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概要
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Absolute configurations are assigned to some cationic <I>cis</I>-[Co(diamine)<SUB>2</SUB>(X)(Y)]<SUP><I>n</I>+</SUP>-type complexes by detecting the direction of the chiral equilibrium shift induced for [Cr(ox)<SUB>3</SUB>]<SUP>3−</SUP> in the presence of these chiral complexes in water–dioxane mixtures. The assignments are found all consistent with those made earlier by CD spectra.
- 公益社団法人 日本化学会の論文
著者
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YONEDA Hayami
Department of Chemistry, Faculty of Science, Hiroshima University
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Miyoshi Katsuhiko
Department Of Chemistry Faculty Of Science Hiroshima University
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Watanabe Kenzo
Department of Chemistry, Faculty of Science, Hiroshima University
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Toda Yoshihisa
Department of Chemistry, Faculty of Science, Hiroshima University
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