A fairly effective environment substance (Co(sep))3+ ion in the Pfeiffer effect of some oxalato complexes of chromium(III).
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概要
- 論文の詳細を見る
A chiral complex ion [Co(sep)]<SUP>3+</SUP> (sep=1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6]eicosane) was found to displace the chiral equilibrium between <I>Δ</I> and <I>Λ</I> enantiomers greatly for moderately optically labile metal complexes [Cr(ox)<SUB>2</SUB>(acac)]<SUP>2−</SUP> and [Cr(ox)<SUB>2</SUB>(gly)]<SUP>2−</SUP> in dioxane–water mixtures.
- 公益社団法人 日本化学会の論文
著者
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YONEDA Hayami
Department of Chemistry, Faculty of Science, Hiroshima University
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Miyoshi Katsuhiko
Department Of Chemistry Faculty Of Science Hiroshima University
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Toda Yoshihisa
Department of Chemistry, Faculty of Science, Hiroshima University
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Sakamoto Yukio
Department of Chemistry, Faculty of Science, Hiroshima University
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