Proton Magnetic Resonance Spectra of Metal Ammine Complexes. III. Interpretation of the Chemical Shifts in Cobalt(III) Pentaammines

スポンサーリンク

概要

• 論文の詳細を見る

• The ammine proton chemical shifts of a series of compounds [CoX(NH<SUB>3</SUB>]<SUP><I>n</I>+</SUP> have been explained quantitatively. The shifts are ascribed to the paramagnetic anisotropy of central cobalt(III) ions. The discrepancies between the calculated and the observed shift values, though small, noted for the <I>trans</I> ammine protons of complexes with X=CN<SUP>−</SUP> and NO<SUB>2</SUB><SUP>−</SUP> may be caused by large inductive effects of these ligands.

• 公益社団法人 日本化学会の論文

著者

• Nakashima Yoshiaki

  Department of Physics, Faculty of Education, Wakayama University

• Nakashima Yoshiaki

  Department of Chemistry, Faculty of Science, Hiroshima University

関連論文

• Ratio of Expression of p16^ to p14^ Correlates with the Progression of Non-small Cell Lung Cancer
• Elevated Serum Vascular Endothelial Growth Factor and Basic Fibroblast Growth Factor Levels in Patients with Thymic Epithelial Neoplasms
• Expression of Periostin, Homologous with an Insect Cell Adhesion Molecule,as a Prognostic Marker in Non-small Cell Lung Cancers
• Proton Magnetic Resonance of Metal Ammine Complexes. IV. Paramagnetic Anisotropy of Cobalt(III) Ions as Exemplified in Proton Chemical Shifts
• Theoretical Study of Proton Chemical Shifts Induced by the Paramagnetic Anisotropy of Cobaltic Ion
• Proton Magnetic Resonance Spectra of Metal Ammine Complexes. III. Interpretation of the Chemical Shifts in Cobalt(III) Pentaammines
• Proton Magnetic Resonance Spectra of Metal Ammine Complexes. I. Cobalt(III) Pentammine Series

スポンサーリンク