Photochemical ethoxycarbonylmethylation of toluene with ethyl chloroacetate.
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概要
- 論文の詳細を見る
UV irradiation of a toluene solution of ethyl chloroacetate under N<SUB>2</SUB> gave an isomeric mixture of ethyl tolylacetates: ortho, 5.2%, meta, 9.6%, para, 0.9% and a trace of diethyl succinate. The reaction under air increased the yields of all the products. Addition of AlCl<SUB>3</SUB> also increased the yields, especially that of ortho; <I>i. e.</I>; 17.9%; meta, 26.5%; para, 10.6%.
- 公益社団法人 日本化学会の論文
著者
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Ogata Yoshiro
Department Of Mechanical Engineering Ii Faculty Of Engineering Kyoto University:(present Address)res
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Hayashi Eiji
Department of Applied Chemistry, Faculty of Engineering, Nagoya University
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