Kinetics of the Acid-Catalyzed Decomposition of Trimeric Acetone Peroxide
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概要
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It was confirmed by the iodometry and gas chromatography that one mole of TAPO in acetic acid was decomposed to three moles of acetone and peroxyacetic acid in the presence of sulfuric acid. The rate of the reaction satisfied the first-order equation with a short induction period. The plot of log<I>k</I> vs. <I>H</I><SUB>o</SUB> gave a straight line with a slope of −1.12. When the concentration of TAPO was high, the amount of peroxyacetic acid was not quantitative, probably because of the transformation of peroxyacetic acid into acetyl peroxide.
- 社団法人 日本化学会の論文
著者
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Ogata Yoshiro
Department Of Mechanical Engineering Ii Faculty Of Engineering Kyoto University:(present Address)res
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Furuya Yoshiaki
Department of Applied Chemistry Faculty of Engineering Nagoya University
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