A new type of iminocarbonylaton of diols, mercaptoalkanol, and dithiol via their dibutylstannyl derivatives.

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概要

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• Reactions of phenyl isothiocyanate with cyclic and acyclic dibutylstannyl dialkoxides derived from several alcohols, such as 1,2- and 1,3-diols and methanol, afforded quantitatively phenyliminocarbonate derivatives with the elimination of dibutylstannyl sulfide. Cyclic organostannyl sulfides, such as 2,2-dibutyl-1,3,2-oxathiastannolane and -dithiastannolane, reacted with phenyl or alkyl isothiocyanate to give 2-imino-oxathiolane (<B>10</B>) and -dithiolane (<B>14</B>), respectively. At higher reaction temperatures, rearrengment and decomposition of products <B>10</B> and <B>14</B> occurred.

• 公益社団法人 日本化学会の論文

著者

• Sakai Shizuyoshi

  Department Of Materials Science Faculty Of Engineering Shizuoka University

• Ishii Yoshio

  Department Of Information Systems Science Faculty Of Engineering Soka University

• Kobayashi Yoshihiro

  Department of Applied Physics, Osaka University, Suita, Osaka 565-0871, Japan

• Niimi Hiroji

  Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University

• Kobayashi Yoshihiro

  Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University

• Sakai Shizuyoshi

  Department of Applied Chemistry, Faculty of Engineering, Shizuoka University

• Sakai Shizuyoshi

  Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University

• Ishii Yoshio

  Department of Industrial Chemistry, Chubu Institute of Technology

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