Reactions of Group IV Organometallic Compounds. XXX. Stepwise Addition of Isocyanates and Isothiocyanates with <I>N</I>-Trimethylstannyl(diphenylmethylene)amine

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概要

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• Stepwise addition of two isocyanates to <I>N</I>-trimethylstannyl(diphenylmethylene)amine, Ph<SUB>2</SUB>C=NSnMe<SUB>3</SUB>, gives 3,4-dihydro-1,3-dialkyl-4,4-diphenyl-6-trimethylstannoxy-1,3,5-triazin-2(1<I>H</I>)-one (II) by a polar [4+2] cycloaddition of the 1/1 adduct and the second isocyanate. The isothiocyanate adducts of Ph<SUB>2</SUB>C=NSnMe<SUB>3</SUB> react with either isocyanates or isothiocyanates to yield the corresponding consecutive insertion products (IV).

• 公益社団法人 日本化学会の論文

著者

• ITOH Kenji

  Department of Applied Chemistry, Graduate School of Engineering, Nagoya University

• MATSUDA Isamu

  Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University

• Ishii Yoshio

  Department Of Information Systems Science Faculty Of Engineering Soka University

• Suzuki Hiroharu

  Department of Applied Chemistry and Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University

• Suzuki Hiroharu

  Department of Synthetic Dhemistry, Faculty of Engineering, Nagoya University

• Matsuda Isamu

  Department of Synthetic Dhemistry, Faculty of Engineering, Nagoya University

• Itoh Kenji

  Department of Applied Chemistry and Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University

• Ishii Yoshio

  Department of Industrial Chemistry, Chubu Institute of Technology

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