Reaction of Group IV Organometallic Compounds. XXXI. The Reaction of <I>N</I>-Trimethylsilyl- and -stannyl(diphenylmethylene)amine with Diketene

スポンサーリンク

概要

• 論文の詳細を見る

• Linear 1/1 adducts and oxazinone derivative were obtained by the reaction of <I>N</I>-trimethylsilyl- and -stannyl(diphenylmethylene)amine; Ph<SUB>2</SUB>C=N–MMe<SUB>3</SUB> (M=Si, Sn) with diketene. Consecutive demetallation reaction by ethanethiol for the organostannyl 1/1 adduct, and by methanol for the organosilyl 1/1 adduct gave a piperidine derivative and an oxazinone derivative, respectively.

• 公益社団法人 日本化学会の論文

著者

• MATSUDA Isamu

  Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University

• Ishii Yoshio

  Department Of Information Systems Science Faculty Of Engineering Soka University

• Suzuki Hiroharu

  Department of Applied Chemistry and Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University

• Suzuki Hiroharu

  Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University

• Matsuda Isamu

  Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University

• Itoh Kenji

  Department of Applied Chemistry and Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University

関連論文

• Multimetallic Activation of Molecular Hydrogen,Leading to Hydrogenation of the Coordinated AzuJenes in Di-, Tri-, and Tetranuclear Ruthenium Carbonyl Complexes
• Carbon-Hydrogen Bond Activation by Triruthenium Carbonyl Species durlng Carbon Monoxide Promoted Elimination of 4,5-Dihydroacemaphthylene from [(μ_2 : η^1 : η^5-C_H_)Ru_3H_2(CO)_7] : Implication of Reaction Intermediates
• Synthesis and Structure Determination of an Oxygen-Functionalized Ruthenacycle: Intramolecular Attack of Coordinated Hydroxide on an Acetylenic Ligand
• Formation of Novel Trinuclear Ruthenium Alkoxo Complexes and a Tetrameric Ruthenium Hydroxo Complex. Crystal Structure of 〔η^5-C_5Me_5)Ru〕_3(μ_3-O)(μ_3-O^iPr) and 〔η^5-C_5Me^5)Ru(μ_3-OH)〕_4
• Synthesis and Reactions of Organoplatinum Compunds C_, C_Pt_n
• Facile Cleavage of Carbon-Palladium Bonds in C_Pd_n with Phosphines and Phosphites. An Alternative Route to (η^2-C_)PdL_2 and Discovery of Fluxionarity Suggesting the Rotation of C_ on the PdL_2 Species in Solution
• Synthesis, Structures, and Reactions of Coordinatively Unsaturated Trinuclear Ruthenium Polyhydrido Complexes, [{Ru(C_5Me_5)}_3(μ-H)_6](Y) (Y = BF_4, CF_3SO_3, 1/2(SO_4), C_6H_5CO_2, CH_3CO_2, B(C_6H_5)_4, PF_6) and [{Ru(C_5Me_5)}_3(μ-H)_3(μ_3-H)_2]
• Effect of AlN Buffer Layer on AlGaN/α-Al_2O_3 Heteroepitaxial Growth by Metalorganic Vapor Phase Epitaxy : Condensed Matter
• Relaxation Process of the Thermal Strain in the GaN/α-Al_2O_3 Heterostructure and Determination of the Intrinsic Lattice Constants of GaN Free from the Strain
• Metalorganie Vapor Phase Epitaxial Growth and Properties of GaN/Al_Ga_N Layered Structures
• Cathodoluminescence Properties of Undoped and Zn-Doped Al_xGa_N Grown by Melalorganic Vapor Phase Epitaxy
• Organopalladium and Platinum Complexes of C_ Bearing Isonitrile Ligands
• Thermal Study of a Silylmethylated Fullerene Leading to Preparation of Its Vacuum Deposited Thin Films
• The Usefulness of the 22-Gauge Safe Guide^【○!R】 Based on Penetration Force and Pattern of Blood Regurgitation
• Catalytic Hydrogenation of Olefins and Acetylenes over C_Pd_n
• Transition-Metal Catalyzed Multi-Component Carbocyclization and Related Reactions of Bifunctional Molecules
• A Novel Laser Scanning Visualization System for Three-Dimensional Representation of Spray Flow-Vectors
• Bimetallic Activation in the Reaction of Dinuclear Ruthenium Complexes with Ethylene
• Massive myoepithelial proliferation (myoepitheliosis) with lumpy deposits of basement membrane material closely associated with apocrine adenosis and ductal carcinoma in situ of the breast
• The Mechanism of Ethylenimine Formation by the Action of Grignard Reagents on Ketoximes
• NMR studies on zerovalent metal .PI.-complexes of dibenzylideneacetone. I. Ligand conformation and bonding in the binuclear palladium complex.
• Reactions of Group IV Organometallic Compounds. XXX. Stepwise Addition of Isocyanates and Isothiocyanates with N-Trimethylstannyl(diphenylmethylene)amine
• Reactions of group V metal compounds with sulfur trioxide.
• Studies of Organosulfur Compounds. IX. The Preparation of Organometal IVb Esters of Aromatic Thio Acid
• The Regioselective Addition of Alcohols to Isoprene with Rhodium Trichloride Hydrates
• Crystal structures of dichlorobis(azocyclohexane)palladium(II) and dichlorobis(azoisopropane)palladium(II).
• Lewis acid mediated synthesis of 2-alkenenitriles using C,N-bis(trimethylsilyl)ketenimine and carbonyl compounds.
• A simple synthesis of .ALPHA.-ylidene .GAMMA.-lactones from .GAMMA.-trimethylsiloxy nitriles.
• A new type of iminocarbonylaton of diols, mercaptoalkanol, and dithiol via their dibutylstannyl derivatives.
• The reactions of group V metal amide with sulfur dioxide.
• Reaction of Group IV Organometallic Compounds. XXXII Modified Synthesis of Imidazolidines with N,N′-Bis(trimethylsilyl)-1,2-diamines
• Reaction of Group IV Organometallic Compounds. XXXI. The Reaction of N-Trimethylsilyl- and -stannyl(diphenylmethylene)amine with Diketene
• Preparation of Diethylaluminium Chelates, R2P(S)–X–AlEt2(X=NMe, S) and Some Reactions with Carbonyl Compounds
• The Japanese version of the modified ACR Preliminary Diagnostic Criteria for Fibromyalgia and the Fibromyalgia Symptom Scale : reliability and validity

もっと見る 閉じる

スポンサーリンク