Reaction of dioxygen complexes with catechols.
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概要
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The square planar dioxygen complexes MO<SUB>2</SUB>(PPh<SUB>3</SUB>)<SUB>2</SUB>(M=Pt, Pd) reacted with catechols at low temperature to give H<SUB>2</SUB>O<SUB>2</SUB> and the corresponding catecholato complexes, characterized by their physical properties, in high yields. A similar treatment of PtO<SUB>2</SUB>(PPh<SUB>3</SUB>)<SUB>2</SUB> with <I>o</I>-substituted anilines afforded the corresponding adducts and H<SUB>2</SUB>O<SUB>2</SUB> in moderate yields.
- 公益社団法人 日本化学会の論文
著者
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Kamiya Yoshio
Department of Applied Chemistry Faculty of Engineering The University of Tokyo
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MUTO Shigeaki
Department of Cardiology and Kidney Center, Jichi Medical School
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Tasaka Kazuaki
Department of Reaction Chemistry, Faculty of Engineering, The University of Tokyo
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