Synthetic studies of laurencin and related compounds. IV. Synthesis of cis-2-ethyl-8-formyl-3,4,7,8-dihydro-2H-oxocin-3-one 3-ethylene acetal and related compounds.

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概要

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• The synthesis of <I>cis</I>-2-ethyl-8-formyl-3,4,7,8-dihydro-2<I>H</I>-oxocin-3-one and its derivatives, key intermediates for synthesis of laurencin, from methyl 2-ethyl-2,5-dihydro-2-furoates is described. The structure and configuration of these compounds and the synthetic intermediates are defined clearly on the basis of the chemical and spectral evidence.

• 公益社団法人 日本化学会の論文

著者

• Masamune Tadashi

  Department Of Chemistry Faculty Of Science Hokkaido University

• Matsue Hajime

  Department Of Cardiovascular Medicine Kyoto Prefectural University School Of Medicine

• Murase Hisashi

  Department of Chemistry, Faculty of Science, Hokkaido University

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