Absorption and fluorescence spectra of anthracenecarboxylic acids. I. 9-Anthroic acid and formation of excimer.
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概要
- 論文の詳細を見る
The absorption spectra of 9-anthroic acid (9-anthracenecarboxylic acid) in ethanol have been measured as a function of solute concentration. It was revealed that 9-anthroic acid forms a hydrogen-bonded dimer. The equilibrium constant for dimer formation was determined to be 6.6×10<SUP>4</SUP> mol<SUP>−1</SUP> 1 in ethanol at 298 K. The fluorescence spectra of 9-anthroic acid have been investigated as a function of concentration and temperature in various solvents. An excimer mechanism was proposed for a broad fluorescence of 9-anthroic acid; the hydrogen-bonded dimer is excited and then associates with an unexcited hydrogen-bonded dimer to form an excited tetramer from which the broad fluorescence occurs.
- 公益社団法人 日本化学会の論文
著者
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Fujii Tsuneo
Department Of Chemistry And Materials Engineering Faculty Of Engineering Shinshu University
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KOMATSU Shigeru
Department of Anatomy Shinshu University School of Medicine
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Iida Toshiko
Department Of Pediatrics Nagoya City University Medical School
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Suzuki Satoshi
Department Of Advanced Cardiac Therapeutics Fukushima Medical University
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Yoshiike Nobuyuki
Department of Industrial Chemistry, Faculty of Engineering, Shinshu University
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Fujii Tsuneo
Department of Chemistry and Material Engineering, Faculty of Engineering, Shinshu University
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Iida Toshiko
Department of Industrial Chemistry, Faculty of Engineering, Shinshu University
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