Prefered orientation and .PI.-bonding of the hydroxyl group in 1,2-benzocycloalken-3-ols.

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概要

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• The various values <I>v</I><SUB>OH</SUB> of 1,2-benzocycloalken-3-ols observed in dilute CCl<SUB>4</SUB> solutions have been explained in terms of the inclination angle of the C–O bond to the plane of the benzene ring (θ) and the conformational isomerism of the OH group with respect to the C–O bond. The <I>v</I><SUB>OH</SUB> shift caused by OH…π bonding is angle-dependent, <I>i.e.</I>, 9 cm<SUP>−1</SUP> if θ=50–90°, or 17 cm<SUP>−1</SUP> if θ=38–45°.

• 公益社団法人 日本化学会の論文

著者

• Mori Nobuo

  Department of Chemistry Tokyo College of Science

• Miyazaki Hitoshi

  Department of Chemistry, Science University of Tokyo

• Kasuya Shin-ichi

  Department of Chemistry, Science University of Tokyo

• Takezawa Toshiyuki

  Department of Chemistry, Science University of Tokyo

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