Intramolecular Hydrogen Bonds. XV. Intramolecular Interaction in <I>N</I>-Alkylaminoalkanonitriles
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概要
- 論文の詳細を見る
The ν<SUB>NH</SUB> values of monomeric alkylmethylamines in carbon tetrachloride solutions are associated with the rotational isomerism about the N–C bond. In the series of <I>N</I>-alkylaminoalkano-nitriles, the intramolecular hydrogen-bonding interaction of the NH group with the π-electrons of the CN group was deduced on the basis of the ν<SUB>NH</SUB> values and a model examination; in the α-series, the NH group probably interacts exclusively, and in the β-series it partially interacts, but in the γ-series it shows no interaction.
- 公益社団法人 日本化学会の論文
著者
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Mori Nobuo
Department of Chemistry Tokyo College of Science
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Tatsumi Junko
Department of Chemistry, Science University of Tokyo
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Asabe Yoshihiro
Department of Chemistry, Science University of Tokyo
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Tsuzuki Yojiro
Department of Chemistry, Science University of Tokyo
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