LiAlH4とダイヤモンド表面のカルボキシル基の化学反応
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概要
- 論文の詳細を見る
We investigated the reactivity of the carbonyl group on a diamond surface. When the oxygenated surface of a diamond powder was treated with LiAlH4, the intensity of the peak assigned to the C=O bond in the IR spectrum decreased, while that of the peak assigned to the O-H bond increased. Reactivity of the C=O bonds on the oxygenated diamond surface depended on the amount of LiAlH4 and the reaction time. However, the peak assigned to the C=O group did not disappear completely. It was found that carbonyl groups on the diamond surface had a lower reactivity toward LiAlH4 than those found in organic compounds. The oxygenated diamond surface could be controlled through organic chemistry.
- 一般社団法人 表面技術協会の論文
著者
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UEHARA Masato
Department of Veterinary Medicine, Tottori University
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Hojo Junichi
Department of Applied Chemistry, Faculty of Engineering, Kyushu University
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Uehara Masato
Department Chemistry & Biochemistry Graduate School Of Engineering Kyushu University
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伊田 進太郎
Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University
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坪田 敏樹
Department of Materials Sciences, Kumamoto Industrial Research Institute
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永田 正典
Department of Materials Sciences, Kumamoto Industrial Research Institute
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MATSUMOTO Yasumichi
Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University
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NAGATA Masanori
Department of Materials Sciences, Kumamoto Industrial Research Institute
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TSUBOTA Toshiki
Department of Applied Chemistry, Faculty of Engineering, Kyushu Institute of Technology
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Tsubota Toshiki
Department Of Applied Chemistry Faculty Of Engineering Kyushu Institute Of Technology
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Matsumoto Yasumichi
Department Of Applied Chemistry & Biochemistry Faculty Of Engineering Kumamoto University
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Hojo Junichi
Department Of Applied Chemistry Faculty Of Engineering Kyushu University
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IDA Shintaro
Department of Applied Chemistry and Biochemistry, Faculty of Engineering, Kumamoto University
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Ida Shintaro
Department Of Applied Chemistry And Biochemistry Faculty Of Engineering Kumamoto University
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Hojo Junichi
Department Chemistry & Biochemistry, Graduate School of Engineering, Kyushu University
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UEHARA Masato
Department of Applied Chemistry, Faculty of Engineering, Kyushu University
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