Microbial Transformation of the Labdanes, cis-Abienol and Sclareol
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概要
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The microbial transformation of cis-abienol and sclareol by a recently isolated soil bacterium, JTS-131, was studied. In the presence of metabolic inhibitors, three new compounds were isolated from the culture broth as degradation products of cis-abienol. They were determined to be (12Z)- labda-12, 14-dien-18-ol, (12Z)-labda-12, 14-dien-18-oic acid and its methylester. Two new compounds were also formed from sclareol in the presence of metabolic inhibitors. They were determined to be 13?A-hydroxylabd-14-en-18-oic acid and 13?A-hydroxylabd-14-en-18-oic acid methylester. As a result of sequence determination experiments, the biotransformation pathways of cis-abienol and sclareol by the bacterium were proposed.
- 社団法人 日本農芸化学会の論文
著者
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Obi Yukiteru
The Central Research Institute Japan Tobacco And Sdlt Public Corporation
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Kisaki Takuro
The Central Research Institute Japan Monopoly Corporation
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Mikami Yoichi
The Central Research Institute Japan Tobacco And Salt Public Corporation
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HIEDA Tadaharu
The Central Research Institute, Japan Tobacco and Salt Public Corporation
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