SOLID-STATE INTERCALATION OF ORGANIC AND INORGANIC SUBSTANCES IN SMECTITES
スポンサーリンク
概要
- 論文の詳細を見る
Our attempts in the preparation of smectite intercalation compounds by solid-solid reactions are reviewed. Various guest substances, including both cationic and nonionic species, metal complexes, and metal sulfide nanoparticles, have been immobilized in the interlayer spaces of smectites. Organoammonium ions were incorporated in the interlayer spaces by the solid-state cation exchange process. The adsorption of nonionic molecules into pristine and organically modified smectites was also possible. Solid-state intercalation was completed within a few minutes at room temperature. The interactions of sulfide ions with the interlayer cations of smectite via adsorption led to smectite-metal sulfide hybrids. Adsorption and in situ formation of both complexes and metal sulfides in smectites were observed, when homoionic (Na(I)-, K(I)-, Rb(I)-, NH_4(I)-, Ca(II)-, Co(II)-, Cu(II)-, Ni(II)-, Cd(II)-, Li(I)-, Al(III)-, Zn(II)- and Mn(II)-) smectites were ground with the appropriate ligands (diimines, 18-crown-6-ether, thioacetamide, thiourea, 8-hydroxyquinoline, as well as sodium sulfide).
著者
-
Khaorapapong Nithima
Department Of Applied Chemistry School Of Science And Engineering Waseda University
-
Ogawa Makoto
Department Mechanical Engineering Ii Shibaura Institute Of Technology
-
Khaorapapong Nithima
Department Of Chemistry And Center Of Excellence For Innovation In Chemistry Faculty Of Science Khon
-
Ogawa Makoto
Department Of Earth Sciences And Graduate School Of Creative Science And Engineering Waseda University
関連論文
- 磁化シｰトプラズマ終端部タｰゲットの熱負荷測定
- Preparation of Iron-Containing Hectorite-Like Swelling Silicate
- Preparation of hectorite-like swelling silicate with controlled layer charge density
- ADSORPTION BEHAVIOR OF PHENOL FOR MONO, BIS AND TRIS(2, 2'-BIPYRIDINE)NICKEL(II)- AND TRIS(ETHYLENEDIAMINE)NICKEL(II)-SAPONITE INTERCALATION COMPOUNDS FROM AQUEOUS SOLUTION
- Preparation of ZnO-core/Nanoporous Silica-shell Particle and the Conversion to Hollow Nanoporous Silica Particle
- Adsorption and Possible Luminescence Detection of Nonylphenol by Eu^-Smectites
- PREPARATION AND THERMAL DECOMPOSITION OF CO(II)-MAGADIITE INTERCALATION COMPOUNDS
- LUMINESCENCE QUENCHING OF TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II) IN THE INTERLAYER SPACE OF SAPONITE BY SULFUR DIOXIDE
- Selective Solid-State Intercalation of cis-trans Isomers into Montmorillonite
- PREPARATION OF MONTMORILLONITE-ALKYLAMINE INTERCALATION COMPOUNDS BY SOLID-SOLID REACTIONS
- PREPARATION OF MONTMORILLONITE-POLYACRYLAMIDE INTERCALATION COMPOUNDS AND THE WATER ABSORBING PROPERTY
- Growth of Nanoporous Silica Spherical Particles by the Stober Method Combined with Supramolecular Templating Approach
- Adsorption of Methylene Blue onto Aluminum-Containing Mesoporous Silica Films Prepared by Rapid Solvent Evaporation Method
- Surface modification of Mesoporous Silica to Control the States of Tris(2,2'-bipyridine)ruthenium(II) Cations
- INCORPORATION OF THIOACETAMIDE INTO THE INTERLAYER SPACE OF MONTMORILLONITE BY SOLID-SOLID REACTIONS
- A Right-Brain/Left-Brain Integrated Associative Processor Employing Convertible MIMD Elements
- Indium-Tin-Oxide Thin Films Prepared by Dip Coating; Dependence of Resistivity on Film Thickness and Annealing Atmosphere : Surfaces, Interfaces, and Films
- TG-DTA-MS of Indium Acetate
- A High-Performance Ramp-Voltage-Scan Winner-Take-All Circuit in an Open Loop Architecture
- A High-Performance Time-Domain Winner-Take-All Circuit Employing OR-Tree Architecture
- Facile synthesis of Zn-Al layered double hydroxide from aqueous suspension of zinc oxide and aluminum hydroxide
- Investigation of the Structure and Stability of an Alcohol-Based Polymer for Hydrogen Storage in the Form of Ions
- Thermal Decomposition of Cerium(III) Acetate Hydrate by a Three-dimensional Thermal Analysis
- Preparation of Well-defined Nanometer-sized Layered Double Hydroxides by Novel pH Adjustment Method Using Ion-exchange Resin
- Syntheses of zirconium-containing titania particles with spherical morphology and uniform size by microfluidic reactions
- "Takotsubo"-shaped cardiomyopathy manifesting as perioperative T-wave inversion
- Controlled Particle Size and Size Distribution of Co-Al Layered Double Hydroxide via the Hydrothermal Urea Method in Aqueous Alcohols
- 1P441 Color Tuning of the Rhodopsin Chromophore Using Clay(17. Light driven system,Poster Session,Abstract,Meeting Program of EABS &BSJ 2006)
- Easily Oxidizable Polysulfide Anion Occluded in the Interlayer Space of Mg/Al Layered Double Hydroxide
- Doubling of serum creatinine : is it appropriate as the endpoint for CKD? Proposal of a new surrogate endpoint based on the reciprocal of serum creatinine
- THE SYNTHESIS OF DIHEXADECYLVIOLOGEN-MONTMORILLONITE-TETRAPHENYLPORPHINE INTERCALATION COMPOUNDS AND THE PHOTOCHEMICAL REACTIONS
- Electrical Conductivity of V_2O_5-CaO-Bi_2O_3 Glasses
- Preparation of Layered Double Hydroxide-Organic Intercalation Compounds by Solid-Solid Reactions
- Synthesis of Au Nanoparticles in the Interlayer Space of a Layered Titanate Intercalated with 2-Aminoethanethiol
- PREPARATION OF LAYERED DOUBLE HYDROXIDES
- SOLID-STATE INTERCALATION OF ORGANIC AND INORGANIC SUBSTANCES IN SMECTITES
- Swelling Behaviors of an Organosilylated Lithium Potassium Titanate in Organic Solvents
- Hepatic Sarcoidosis with an Increased Serum Level of Immunoglobulin G4
- Photoprocesses in mesoporous silicas prepared by a supramolecular templating approach
- Luminescence of Tris(8-quinolinato)aluminum(III) (Alq_3) Adsorbed into Mesoporous Silica
- Right-Brain/Left-Brain Integrated Associative Processor Employing Convertible Multiple-Instruction-Stream Multiple-Data-Stream Elements