ADSORPTION BEHAVIOR OF PHENOL FOR MONO, BIS AND TRIS(2, 2'-BIPYRIDINE)NICKEL(II)- AND TRIS(ETHYLENEDIAMINE)NICKEL(II)-SAPONITE INTERCALATION COMPOUNDS FROM AQUEOUS SOLUTION

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概要

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• Adsorption of phenol on mono, bis and tris(2, 2'-bipyridine)nickel(II)- and tris(ethylenediamine)-nickel(II)-saponite intercalation compounds from aqueous solution was examined. Mono, bis and tris(2, 2'-bipyridine)nickel(II)-saponites were prepared by the reactions of Ni(II)-form of a synthetic saponite (Sumecton SA) with 2, 2'-bipyridine at the molar 2, 2'-bipyridine to Ni(II) ratios of 1:1, 2:1 and 3:1. Tris(ethylenediamine)nickel(II)-saponite was prepared by the reactions of the Ni(II)-saponite with ethylenediamine at the molar ratio of 3:1 (ethylenediamine:Ni(II)). X-Ray diffraction and thermal analysis indicated that 2, 2'-bipyridine and ethylenediamine were intercalated into Ni(II)-saponite to form mono, bis and tris(2, 2'-bipyridine)nickel(II) and tris(ethylenediamine)nickel(II) complexes. The adsorption isotherms of phenol for the mono, bis and tris(2, 2'-bipyridine)nickel(II)-saponites followed Langmuir type, indicating strong adsorbate-adsorbent interactions. The basal spacings of the mono, bis and tris(2, 2'-bipyridine)nickel(II)-saponites did not change by the adsorption of phenol, indicating that the adsorbed phenol existed in the interlayer micropore formed by the pillaring with the complexes. The adsorption of phenol on the tris(ethylenediamine)nickel(II)-saponite was less effective than those on the (2, 2'-bipyridine)nickel(II)-saponites, suggesting that the interactions between pyridine rings and phenol played an important role in the adsorption of phenol.

• 日本粘土学会の論文

著者

• OKADA TOMOHIKO

  Department of Chemistry and Material Engineering, Shinshu University

• OGAWA Makoto

  Department of Nuclear Engineering, School of Engineering, Tokai University

• Okada Tomohiko

  Department Of Chemistry And Material Engineering Faculty Of Engineering Shinshu University

• MORITA TAKAO

  Graduate School of Science and Engineering, Waseda University

• Ogawa Makoto

  Waseda Univ. Tokyo Jpn

• Morita Takao

  Graduate School Of Science And Engineering Waseda University

• Okada Tomohiko

  Shinshu Univ. Nagano Jpn

• Ogawa Makoto

  Department Of Earth Environment And Resources Sciences Graduate School Of Creative Science And Engin

• Ogawa Makoto

  Department Mechanical Engineering Ii Shibaura Institute Of Technology

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