3-90-1 バイオマス初期熱分解生成物化学組成の詳細分析と二次気相反応シミュレーション(Session 3 バイオマス等,ポスター発表)

概要

論文の詳細を見る
In an effort to interpret secondary reactions in biomass thermochemical conversions at mechanistic level, homogeneous partial oxidations of nascent volatiles from rapid pyrolysis of Japanese cedar sawdust at 973 K were numerically simulated using a detailed chemical kinetic model that included more than 500 chemical species and more than 7000 elementary reactions. For a better molecular description of the nascent volatiles, a detailed analysis of the pyrolysates was performed using a GC/MS. More than seventy compounds were identified and approximately twenty of which were included in the kinetic model. It was found that the numerically simulated concentrations of major species were in broad agreement with those measured. Further improvements in the predictive capabilities are expected by including more detailed information on chemical composition of nascent volatiles to the simulation input.
一般社団法人日本エネルギー学会の論文
2009-07-30