O-504 セルロース気相熱分解反応における芳香族炭化水素の生成機構(セッション5:技術4:ガス化,研究発表,(口頭発表))

概要

論文の詳細を見る
We found that alkyne and diene compounds such as acetylene, propyne, and propadiene are included in the products from the primary pyrolysis of cellulose even at temperature as low as 500℃. These are important precursors for tarry constituents like aromatic hydrocarbons found in the vapor phase cracking of cellulose which is originally free from aromatic structures. The reaction pathway leading to first aromatic ring via propyne and propadine from primary pyrolysates of cellulose was discussed based on the experimental results with pyrolysis-GC as well as the kinetic modeling with detailed chemistry.
一般社団法人日本エネルギー学会の論文
2012-01-18