26 焙焼食品中のPyrazine生成に関連したアミノカルボニル反応
スポンサーリンク
概要
- 論文の詳細を見る
A number of simple alkylated pyrazines has been focused as flavor components of roasted foodstuffs. As one of Mechanistic studies on the formation of alkylpyrazine in roasted foodstuffs, a model reaction of α-ketocarbinol with α-amino acid was investigated. Reaction of acetoin and D,L-phenylalanine produced tetramethylpyrazine(TMP) in high yield. Intermediates [III],[VI],[VII] and [VIII] shown in scheme 6, were isolated from the reaction mixture, and they were converted in to TMP in high yield respectively. The other compounds such as phenylacetaldehyde, formic acid, carbondioxide, phenethylamine and ethylbenzine were also detected in the reaction. Thus a plausible mechanism of the formation of TMP was proposed as the scheme 6.
- 天然有機化合物討論会の論文
- 1978-08-22
著者
関連論文
- 生物活性を有する天然物の分離研究(第5報)白樺皮中の抗糸状菌性成分について
- 生物活性を有する天然物の分離研究(第4報)木槿皮中の抗糸状菌性成分について
- 2 アミノ酸熱分解物中に含まれる変異原物質 : 分離・構造・合成および生物活性
- タール剤の成分研究(第9報)アミノ酸の乾留による生理活性物質の生成 その3チロシン乾留成績体中の抗糸状菌性物質について
- タール剤の成分研究(第8報)アミノ酸の乾留による生理活性物質の生成 その2フェニールアラニン乾留成績体中の抗糸状菌性物質について
- タール剤の成分研究(第7報)各種アミノ酸の乾留による生理活性物質の生成およびトリブトファン乾留成績体中の抗糸状菌性物質について
- タール剤の成分研究(第6報)魚粉乾留タール中の抗糸状菌性物質について
- タール剤の成分研究(第3報)大豆粕乾留タール中の抗ヒスタミンおよび抗糸状菌性物質について
- P-57 New Zealand (NZ)産毒化貝中の新規水溶性神経毒の分離及び構造についての研究(ポスター発表の部)
- Study on Pharmacological Effect of bile Salts, Sodium Scymnol Sulfate, from Rhizoprionodon acutus. I. Effect of Scymnol, Chimaerol and Sodium Scymnol Sulfate on Cerebral Anoxia
- Study on the Bile Salt, Sodium Scymnol Sulfate, from Rhizoprionodon acutus. IV. Structures of Chimaerol and Sodium Chimaerol Sulfate in the Bile of Lamna ditropis and Rhizoprionodon acutus
- Studies on Active Substances in Herbs Used for Hair Treatment. I. Effects of Herb Extracts on Hair Growth and Isolation of an Active Substance from Polyporus umbellatus F.
- Modification of the Amino Group of Guanosine by Methylglyoxal and Other α-Ketoaldehydes in the Presence of Hydrogen Peroxide
- Study on the Bile Salt, Sodium Scymnol Sulfate, from Lamna ditropis. III. The Structures of a New Sodium Scymnol Sulfate and New Anhydroscymnols
- Studies on Active Principles of Tars. X. The Structures and Some Reactions of Antifungal Constituents in Pix Pini
- Study on the Bile Salt, Sodium Scymnol Sulfate, from Rhizoprionodon actuatus. II. The Structures of Scymnol, Anhydroscymnol and Sodium Scymnol Sulfate
- ISOLATION AND STRUCTURAL DETERMINATION OF A MUTAGENIC SUBSTANCE IN CREATINE PYROLYSATE
- Studies on the Antihemostatic Substances in Herbs Classified as Hemostatics in Traditional Chinese Medicine. I. : On the Antihemostatic Principles in Sophora japonica L.
- 止血に用いられる生薬の有効成分に関する研究(第10報)熱処理止血生薬の止血効果
- アブラソコムツ(Lepidocybium flavobrunneum)のワックス成分と医薬品又は化粧品基剤への応用
- バイ(海つぼ)毒素に関する研究
- Isolation of an Anti-histaminic Substance from Green-Lipped Mussel (Perna canaliculus)
- FIRST EVIDENCE OF TOXIN PRODUCTION BY BACTERIA IN A MARINE ORGANISM
- Isolation of a New Toxin, Prosurugatoxin, from the Toxic Japanese Ivory Shell, Babylonia japonica
- バイ(海つぼ)の食中毒原因毒素 (動物の毒)
- コンブの強心成分
- Isolation of Neosurugatoxin from the Japanese Ivory Shell, Babylonia japonica
- 17 毒化バイ貝Babylonia Japonicaよりの新有毒成分Neosurugatoxinの分離及び構造決定
- 熱分解による発癌物質(突然変異原物質)の生成 (天然物化学1980B)
- タール剤の成分研究(第2報)鶏卵黒焼および乾留タール中の抗糸状菌性物質について
- ISOLATION AND STRUCTURAL DETERMINATION OF MUTAGENIC SUBSTANCES IN COAL TAR
- A Potent Mutagen isolated from a Pyrolysate of L-Ornithine
- 26 焙焼食品中のPyrazine生成に関連したアミノカルボニル反応
- Studies on Microdetermination of Halogen and Sulfur in Organic Compounds. Tungsten Trioxide, a Novel Catalyst by Combustion Tube Method
- 4-Nitroquinoline 1-Oxideおよび4-Hydroxyaminoquinoline1-Oxideの化学 (ヘテロ環の化学-5-)
- Studies on Anticancer Principles in Chinese Medicines. II. Cytotoxic Principles in Biota orientalis (L.) ENDL. and Kaempferia galanga L.
- Studies on Bioactive Substances in Crude Drugs Used for Arthritic Diseases in Traditional Chinese Medicine. III. Isolation and Identification of Anti-inflammatory and Analgesic Principles from the Whole Herb of Pyrola rotundifolia L.
- Studies on Bioactive Substances in Crude Drugs Used for Arthritic Diseases in Traditional Chinese Medicine. II. Isolation and Identification of an Anti-inflammatory and Analgesic Principle from the Root of Angelica pubescens MAXIM.
- 〓風湿薬中の生理活性成分に関する研究(第1報)〓風湿薬の抗炎症, 鎮痛作用について
- 中薬の制癌作用及び制癌作用成分に関する研究(第1報)治癌中薬の制癌作用
- 止血に用いられる生薬の有効成分に関する研究(第2報)田七の止血作用成分について
- 止血に用いられる生薬の有効成分に関する研究(第1報)止血に用いられる生薬の止血効果
- トリカブト根中の強心成分に関する研究(第1報)Higenamineの単離およびその構造
- 異項環化合物の光化学反応(第2報) : 4-Nitroquinoline 1-OxideとNitrosylchlorideの反応
- 米糠タール中の抗糸状菌成分について
- Studies on Antihemorrhagic Substances in Herbs Classified as Hemostatics in Chinese Medicine. V. On Antihemorrhagic Principle in Biota orientalis (L.) ENDL.
- Studies on Antihemorrhagic Substances in Herbs Classified as Hemostatics in Chinese Medicine. IV. On Antihemorrhagic Principles in Hypericum erectum THUNB.
- Studies on the Antihemorrhagic Substances in Herbs Classified as Hemostatics in Chinese Medicine. VIII. : On the Antihemorrhagic Principle in Nelumbins Receptaculum
- Studies on the Antihemorrhagic Substances in Herbs Classified as Hemostatics in Chinese Medicine. IX. : On the Antihemorrhagic Principles in Typha lactifolia L.
- Study on the Bile Salt Sodium Scymnol Sulfate, from Rhizoprionodon acutus
- Studies on Antihemorrhagic Substances in Herbs Classified as Hemostatics in Chinese Medicine. VII. On the Antihemorrhagic Principle in Cirsium japonicum DC(Medicinal Chemistry,Chemical)
- Studies on Antihemorrhagic Substances in Herbs Classified as Hemostatics in Chinese Medicine. VI. On the Antihemorrhagic Principle in Sophora japonica L(Medicinal Chemistry,Chemical)
- Studies on Active Substances in Herbs Used for Oketsu ("Stagnant Blood") in Chinese Medicine. VI. On the Anticoagulative Principle in Paeoniae Radix(Medicinal Chemistry,Chemical)
- Studies on Active Substances in Herbs Used for Oketsu ("Stagnant Blood") in Chinese Medicine. V. On the Anticoagulative Principle in Moutan Cortex(Medicinal Chemistry,Chemical)
- オクテット
- Synthesis of Mutagens isolated from Tryptophan Pyrolysate and of Some Analogs, 3-Amino-5H-pyrido [4,3-b] indoles
- Synthesis of Mutagenic Principles Isolated from L-Glutamic Acid Pyrolysate
- Synthesis and Some Reactions of 6-Bromooxindole
- Studies on Antihemorrhagic Substances in Herbs Classified as Hemostatics in Chinese Medicine. III. On the Antihemorrhagic Principle in Sanguisorba officinallis L.
- 葛澱粉晒し液からのイソフラボン誘導体の回収
- Identification of a Reactive Metabolite of the Mutagen, 2-Amino-3-methylimidazolo [4,5-f] quinoline
- 植物および動物タール中の有効成分とその合成
- 治癌中薬に関する研究-3-菱実中のHeLa細胞に対する細胞毒性成分について
- Studies on Active Substances in the Herbs Used for Oketsu ("Stagnant Blood") in Chinese Medicine. IV. On the Anticoagulative Principle in Rhei Rhizoma
- Studies on Active Substances in the Herbs Used for Oketsu ("Stagnant Blood") in Chinese Medicine. III. On the Anticoagulative Principles in Curcumae Rhizoma
- Studies on Active Substances in the Herbs Used for Oketsu ("Stagnant Blood") in Chinese Medicine. II. On the Anticoagulative Principle in Persicae Semen
- 〓血に用いられる生薬の有効成分に関する研究(第1報)〓血に用いられる生薬の抗凝血活性
- 最近の静岡県我入道産バイ貝の毒性および毒成分
- バイの毒化機構に関する研究-1-スルガトキシン様物質を産生する細菌の単離
- くさやに関する研究-1-くさや汁の防腐効果について