Diamond/SiC複合体のHIP合成と超高圧アンビルへの応用(<特集>極限環境)

概要

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Using a hot isostatic pressing (HIP) technique, diamond/SiC composites were synthesized from diamond and Si powders. At an HIP condition of 1450℃ and 100MPa, a pressure much lower than that of the diamond stability field, diamond powders react with molten Si to form well-sintered diamond/SiC composites. Cubes of the composites with 15mm edge length were thereby fabricated, and an application to the second stage anvils in a Kawai-type high-pressure apparatus was attempted. The anvils were proved to be hard enough for the generation of pressures up to 30GPa. For high-pressure and high-temperature in-situ X-ray experiments using synchrotron radiation, a hybrid anvil system using 4 cubes of the composites and 4 of conventional WC was introduced and heating experiments up to 1600℃ at 20GPa became possible. Because the diamond/SiC composites are transparent to X rays, the present system is applicable not only to diffraction studies but also to radiographic studies that need a larger window for an X-ray image.
社団法人日本材料学会の論文
2006-03-15