Preparation of Nicotyrine via Catalytic Dehydrogenation of Nicotine(Organic Chemistry)
スポンサーリンク
概要
- 論文の詳細を見る
In our previous papers, 1) syntheses of the derivatives of nicotine (1) have been investigated. The pyrolysis of 1 was one of the methods to prepare nicotine analogues which possessed unsaturation in the pyrrolidine ring. Nicotyrine (2) and myosmine (3) were reported to be prepared via pyrolysis of 1 over quartz sand at high temperature ( ?? 570°C).2) However, their yields were very low, and several by-products were detected in the reaction mixture. In this paper, we report the selective preparation of 2 by catalytic dehydrogenation of 1 over hydrous zirconium oxide and its analogues.
- 社団法人日本農芸化学会の論文
- 1988-10-23
著者
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Kuno H
Japan Tobacco Inc. Kanagawa
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Kuno Hideyuki
Life Science Research Laboratory Japan Tobacco Inc.
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Takahashi K
Osaka Univ. Osaka
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Shibagaki Makoto
Life Science Research Laboratory, Japan Tobacco Inc.
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Takahashi K
Life Science Research Laboratory Japan Tobacco Inc.
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TAKAHASHI Kyoko
Life Science Research Laboratory, Japan Tobacco INC.
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MATSUSHITA Hajime
Life Science Research Laboratory, Japan Tobacco INC.
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Shibagaki M
Life Science Research Laboratory Japan Tobacco Inc.
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Shibagaki Makoto
Life Science Research Laboratory Japan Tabacco Inc.
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Matsushita Hajime
Life Science Research Laboratory Japan Tobacco Inc.
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Matsushita Hajime
Life Science Research Laboratory Japan Tabacco Inc.
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Shibagaki Makoto
Life Science Research Laboratory
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Takahashi Kyoko
Life Science Research Laboratory
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Kuno Hideyuki
Life Science Research Laboratory
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Matsushita Hajime
Life Science Research Laboratory
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