N→N Alkyl and Glycosyl Migration of Purines and Pyrimidines. III. N→N Alkyl and Glycosyl Migration of Purine Derivatives
スポンサーリンク
概要
- 論文の詳細を見る
Alkyl and glycosyl migration reactions of N-1,N-3,N-7 and N-9 substituted derivatives of adenine, N^6,N^6-dimethyladenine, N^2-acetylguanine and purine were demonstrated. In addition, the chemical shifts of these derivatives in nuclear magnetic resonance (NMR) were determined and the frontier π-electron densities of nitrogens in purine ring were calculated by simple LCAOMO method. These results provided the order of thermodynamical stability and kinetical favour of the derivatives on the alkylation reaction.
- 社団法人日本薬学会の論文
- 1970-07-25
著者
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清水 文治
Central Research Laboratories of Sankyo Co., Ltd.
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宮木 美知子
Central Research Laboratories Sankyo Co. Ltd.
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清水 文治
Central Research Laboratories Sankyo Co. Ltd.
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