アンモニウムイリド化学の新展開
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概要
- 論文の詳細を見る
Benzylammonium N-alkylides were generated by reaction of N-[1-(trimethylsilyl) alkyl] benzylammonium salts with cesium fluoride in DMF or HMPA, and their rearrangement products were investigated. [2,3] Sigmatropic rearrangement of the ylides initially occurred to give isotoluene derivatives and then they were transformed into Sommelet-Hauser rearrangement products and/or Stevens products. The isotoluenes having bicyclic structures were stable at room temperature and aromatized with the aid of a base. The relationship between the configuration of cyclic ammonium ylides and the rearrangement paths is described.
- 社団法人日本薬学会の論文
- 1994-11-25
著者
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佐藤 義朗
名古屋市立大学薬学部
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白井 直洋
名古屋市立大学薬学部
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白井 直洋
Faculty of Pharmaceutical Sciences, Nagoya City University
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白井 直洋
Faculty Of Pharmaceutical Sciences Nagoya City University
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