Rearrangement of N, N-Dimethyl(1- of 2-naphthylmethyl)ammonium N-Methylide
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概要
- 論文の詳細を見る
N, N-Dimethyl-(1- or 2-naphthylmethyl)ammonium N-methylide (2a, b) produced from N, N-dimethyl-N-[(trimethylsilyl)methyl](1- or 2-nephthylmethyl)ammonium iodide (1a, b) with CsF in N, N-dimethylformamide, was rearranged to 2[(dimethylamino)methyl]-1,2-dihydro-1-naphtholidene (3a) or 1-[(dimethylamin)methyl]-1,2-dihydro-2-naphtholidene (3b), respectively, in high yield. Aromatization of 3a, b to the Sommelet-Hauser products(4a, b) occurred with the aid of KOH or heating.
- 社団法人日本薬学会の論文
- 1994-06-15
著者
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佐藤 義朗
名古屋市立大学薬学部
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小山 志代美
Faculty of Pharmaceutical Sciences, Nagoya City University
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白井 直洋
Faculty of Pharmaceutical Sciences, Nagoya City University
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佐藤 義朗
Faculty of Pharmaceutical Sciences, Nagoya City University
-
小山 志代美
Faculty Of Pharmaceutical Sciences Nagoya City University
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白井 直洋
Faculty Of Pharmaceutical Sciences Nagoya City University
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