Studies on Glycosylation. II. A S-Glycosylation by Use of Stannic Chloride

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概要

• 論文の詳細を見る

• Application of the Helferich method to the preparation of thioglycosides was performed in dichloroethane at room temperature by use of SnCl_4 as catalyst. The reaction gave 1-thio-β-D-glucopyranoside from penta-O-acetyl-β-D-glucopyranose and thiophenol in good yield. However, the similar reaction with methyl 1,2,3,4-tetra-O-acetyl-β-D-glucopyranuronate and thiophenol gave an unpredicted product, 3,4-di-O-acetyl-6-methoxy 6-thiophenyl-α-D-glucopyranose 1,2-(phenylthio orthoacetate). The structure was confirmed by analytical and spectral data.

• 社団法人日本薬学会の論文
• 1976-04-25

著者

• 浜田 昭

  School of Pharmaceutical Sciences, Showa University

• 本間 喜久子

  School of Pharmaceutical Sciences, Showa University

• 浜田 昭

  School Of Pharmaceutical Sciences Showa University

• 本間 喜久子

  School Of Pharmaceutical Sciences Showa University

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