Total Synthesis of (±)-Carpesiolin

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Total synthesis of (±)-carpesiolin (1) is described using a new and general synthetic route to helenanolide sesquiterpenes. The scheme includes the stereocontrolled introduction of the C-10 α-methyl group in the perhydroindanone (3) and its conversion to the perhydroazulenone (4) via the regiospecific ring expansion reaction.
公益社団法人日本薬学会の論文
1981-09-25

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Total Synthesis of (±)-Carpesiolin

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