Thiosteroids. XXVI. Steroidal Transannular 2,5-Epoxide and Related Compounds
スポンサーリンク
概要
- 論文の詳細を見る
A number of 3α-substituted (H, OH, OAc or SCN)-2β, 5α-dihydroxycholestanes upon treatment with mesyl chloride and pyridine gave the corresponding 2α, 5α-epoxides. These structures were established by the nuclear magnetic resonance spectra and by chemical conversions. In addition, the reaction of a series of 5α-hydroxy-2α, 3α-epoxysteroids with hydrobromic acid leading to the 3α-hydroxy-2α, 5α-epoxysteroids was studied. The reaction mechanism was also discussed.
- 公益社団法人日本薬学会の論文
- 1970-06-25
著者
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米野 太一郎
Shionogi Research Laboratory, Shionogi & Co., Ltd.
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岩倉 彦三
Shionogi Research Laboratory Shionogi & Co. Ltd.
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井谷 光
Shionogi Research Laboratories Shionogi & Co. Ltd.
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鍋山 喜代子
Shionogi Research Laboratory, Shionogi & Co., Ltd.
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鍋山 喜代子
Shionogi Research Laboratory Shionogi & Co. Ltd.
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米野 太一郎
Shionogi Research Laboratory Shionogi & Co. Ltd.
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