A Novel Oxidation-Acetylation of Hydroxysulfides
スポンサーリンク
概要
- 論文の詳細を見る
A novel oxidative acetylation was found in the oxidation of hydroxyalkyl sulfides (IIIa to VIIIa) with 30% H_2O_2-AcOH. Whereby it was concluded that when the hydroxyl can conformationally approach the sulfur atom the sulfide is prone to acetylation during the oxidation. An oxidation-acetylation mechanism has been proposed for the reaction as summarized in Chart 4.
- 社団法人日本薬学会の論文
- 1970-02-25
著者
-
増田 克忠
武田薬品工業株式会社研究開発本部化学研究所
-
増田 克忠
Chemical Research Laboratories Research And Development Division Takeda Chemical Industries Ltd.
-
沼田 光雄
Chemical Research Laboratories, Research and Development Division, Takeda Chemical Industries, Ltd.
-
山岡 正義
Chemical Research Laboratories, Research and Development Division, Takeda Chemical Industries, Ltd.
-
沼田 光雄
Chemical Research Laboratories Research And Development Division Takeda Chemical Industries Ltd.
-
山岡 正義
Medicinal Research Laboratories Central Research Division Takeda Chemical Industries Ltd.
関連論文
- Synthesis of New Cephalosporins with Potent Antibacterial Activities
- Studies on Azetidine Derivatives. II. Reactions and Stereochemistry of 3-Substituted 1-Cyclohexyl-2-phenylazetidines
- Studies on Azetidine Derivatives. I. Synthesis of 3-Substituted Azetidine Derivatives
- Studies on Mesoionic Compounds. III. Synthesis of Ψ-3-Aryl-5-imino-3,5-dihydro-1-oxa-2,3,4-triazole Hydrochlorides and Their Derivatives
- Studies on Mesoionic Compounds. II. Synthesis of N-Acyl Derivatives of 3-Dialkylaminosydnonimines
- Studies on Mesoionic Compounds. I. Synthesis of 3-Dialkylaminosydnonimines
- S-(α-Acyloxyalkyl)thiamine誘導体の合成 : ビタミンB_1および諸関係化合物の研究(CVIII)
- 15.非対称型Thiamine disulfide類の合成における一知見
- 22.S-(α-Acyloxyalkyl)thiamineの合成(一般研究発表要旨)
- 14.ビタミンB_1の強アルカリ域における変化(第120回協議会研究発表要旨)
- 34.ビタミンB_1類とアンモニアとの反応(第12回大会研究発表要旨)
- 48.Poliodin(Glutamylcholineの製剤)の研究(I) : Glutamylcholineの合成について(第59回協議会研究報告要旨)
- A Novel Oxidation-Acetylation of Hydroxysulfides
- 103.ビタミンB_1拮抗体の合成(日本ビタミン学会第17回大会研究発表要旨)
- Hindered Internal Rotation of N, N-Dimethylpropylamines
- Synthesis of Nereistoxin and Related Compounds. II
- 202 Thiamine拮抗物質の抗コクシジウム効果 (第61回日本獣医学会記事)
- アゼチジンの化学