Formal Synthesis of (+)-Grandisol from Levoglucosenone

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概要

• 論文の詳細を見る

• (+)-Grandisol, which is a component of the male-produced pheromone of the boll weevil, Anthonomus grandis, was synthesized from levoglucosenone. The key steps in the synthesis are the intramolecular diatereoselective four-membered ring construction and the Baeyer-Villiger oxidation. The 17-step procedure led to a known synthetic intermediate of (+)-grandisol.

• 公益社団法人日本薬学会の論文
• 1993-05-15

著者

• 古関 幸史

  Life Science Research Laboratory Japan Tobacco Inc.

• 岡野 耕二

  Life Science Research Laboratory Japan Tobacco Inc.

• 川上 浩

  Life Science Research Laboratory Japan Tobacco Inc.

• 松本 克也

  Life Science Research Laboratory Japan Tobacco Inc.

• 惠畑 隆

  Life Science Research Laboratory, Japan Tobacco Inc.,

• 松下 肇

  Life Science Research Laboratory, Japan Tobacco Inc.,

• 惠畑 隆

  Life Science Research Laboratory Japan Tobacco Inc.

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