Telomers (n=3) of Vinylene Carbonate with Tetrachloromethane as Novel Synthetic Intermediates for Aldo-heptoses and -octoses
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概要
- 論文の詳細を見る
Stereochemistry of four isomeric telomers (n=3) (3), arising from the free-radical telomerization of vinylene carbonate with carbon tetrachloride, was unequivocally established as all trans addition forms (3a, b, c and d), based on their conversions to the enolphosphates (4) and the heptitols (8). Synthetic potential of the telomers (3) for aldoheptoses and -octoses has been shown by transforming for example the isomer b into"racemic"D-glycero-L-gulo-and D-glycero-D-ido-heptoses and D-threo-D-ido-octose in reasonable yields.
- 公益社団法人日本薬学会の論文
- 1978-07-25
著者
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滝沢 武夫
Faculty of Pharmaceutical Sciences, University of Tokyo
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国枝 武久
Faculty of Pharmaceutical Sciences, University of Tokyo
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滝沢 武夫
Faculty Of Pharmaceutical Sciences University Of Tokyo:(present Address) Department Of Chemistry Uni
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新居 泰
Faculty Of Pharmaceutical Sciences University Of Tokyo
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国枝 武久
Faculty Of Pharmaceutical Sciences Kumamoto University
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