Studies on the Alkaloids of Menispermaceous Plants. CCXLI. Synthesis of Cycleanine. (2). Bischler-Napieralski Reaction of N-Acyl-3,4-dimethoxy-5-(4-substituted-phenoxy)-β-phenethylamines

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概要

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• During the course of the studies for synthesis of II, the Ullmann reaction product of 8-bromoarmepavine, Bischler-Napieralski reaction of amide XI was carried out. Characterization of the product was effected by metallic sodium-liquid ammonia fission reaction. It was found that the isoquinoline ring-closure of such an amide formulated as XVIII occurred onto both o-and p-positions to the phenoxyl grouping, that is, the direction of the ring-closure was unexpectedly affected by substituent borne on 4-position of the phenoxyl grouping.

• 公益社団法人日本薬学会の論文
• 1968-01-25

著者

• 富田 真雄

  Kyoto College Of Pharmacy

• 冨士谷 憲徳

  Faculty of Pharmaceutical Sciences, Kyoto University

• 富田 真雄

  Faculty of Pharmaceutical Sciences, Kyoto University

• 青柳 良明

  Faculty of Pharmaceutical Sciences, Kyoto University

• 坂谷 芳郎

  Faculty of Pharmaceutical Sciences, Kyoto University

• 青柳 良明

  Faculty Of Pharmaceutical Sciences Kyoto University

• 冨士谷 憲徳

  Kyoto Pharmaceutical University

• 坂谷 芳郎

  Faculty Of Pharmaceutical Sciences Kyoto University

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