Structure and Absolute Configuration of Kessanol and 8-epi-Kessanol
スポンサーリンク
概要
- 論文の詳細を見る
The sesqutierpenoid alcohols, kessanol and 8-epi-kessanol, isolated from certain kinds of Japanese valerian, have been shown to be 2-deoxykessyl glycol (I;R=H) and 2-deoxy-8-epi-kessyl glycol (III;R=H), respectively, by physicochemical studies of the alcohols and their oxidation products, kessan-8-one(II). The mixture of the wwo alcohols (I and III;R=H) has been synthesized from kessyl glycol (IV;R=H, R'=H). The configuration of the hydroxyl at C-8 as being α in kessanol and β in 8-epi-kessanol has been confirmed by application of the dissymmetry rule.
- 1967-03-25
著者
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ヒキノ ヒロシ
Pharmaceutical Institute Faculty Of Medicine Tohoku University
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曳野 靖子
東北大・薬
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曳野 靖子
Pharmacentical Institute, Tohoku University
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竹本 常松
Pharmaceutical Faculty Tokushima Bunri University
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小野 雅康
東北大学医学部薬学科
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竹下 保義
東北大学医学部薬学科
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竹下 保義
Pharmaceutical Institute, School of Medicine, Tohoku University
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白田 和子
Pharmaceutical Institute, Tohoku University School of Medicine
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小野 雅康
Pharmaceutical Institute, Tohoku University School of Medicine
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白田 和子
Pharmaceutical Institute Tohoku University School Of Medicine
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