The Use of Radioactive Element. II. Decomposition of 1,4-Dibenzoyl-thiosemicarbazide and 1,4-Dibenzoylsemicarbazide with Alkali.

スポンサーリンク

概要

• 論文の詳細を見る

• 1,4-Dibenzoylthiosemicarbazide (II) is converted by the action of alkali principally into 3-phenyl-5-mercapto-1,2,4-triazole (IV) and benzoic acid. The reaction route was studied by using ^<14>C-tracer technique. It was thereby found that (II) affords 1-benzoyl-thiosemicarbazide (A) and benzoic acid in the first step and (A) further cyclizes to (IV), while a part of (A) decomposes into benzoic acid and ammonia. 1,4-Dibenzoylsemicarbazide also behaves in analogous manner.

• 公益社団法人日本薬学会の論文
• 1957-12-20

著者

• 杉井 通泰

  Institute for Chemical Research, Kyoto University

• 中井 利三郎

  Institute for Chemical Research, University of Kyoto

• 杉井 通泰

  Institute For Chemical Research Kyoto University

• 中尾 英雄

  Takamine Research Laboratory Sankyo Co. Ltd.

• 中井 利三郎

  Institute For Chemical Research University Of Kyoto

関連論文

• Isolation and Biosynthesis of L-Homomethionine (L-5-Methylthionorvaline)
• New Sulfur containing Amino Acids in Cabbage : Isolation and Identification of L-Homomethionine (L-5-Methylthionorvaline)
• Isolation of γ-L-Glutamyl-S-allylmercapto-L-cysteine and S-Allylmercapto-L-cysteine from Garlic
• 12 アリウム属に於ける含硫アミノ酸の生合成
• Isolation of (-) S-Propenyl-L-cysteine from Garlic
• Biosynthesis of S-Methyl-L-cysteine and S-Methyl-L-cysteine Sulfoxide from Methionine in Garlic
• Metabolism of S-(2-Carboxypropyl) glutathione in Rabbit
• γ-L-Glutamyl-S-allyl-L-cysteine, a New γ-Glutamyl Peptide in Garlic(■)
• Metabolic Incorporation of L-Valine-[^C] into S-(2-Carboxypropyl) glutathione and S-(2-Carboxypropyl) cysteine in Garlic.(51)
• Isolation of (-) S-Allyl-L-cysteine from Garlic
• New γ-Glutamyl Peptides in Garlic
• The Use of Radioactive Element. IV. Decarboxylation of Carboxylic-Carbonic Anhydride
• The Use of Radioactive Element. III. Decarboxylative Acylation of Phenylacetic Acid.
• The Use of Radioactive Element. II. Decomposition of 1,4-Dibenzoyl-thiosemicarbazide and 1,4-Dibenzoylsemicarbazide with Alkali.

もっと見る 閉じる

スポンサーリンク