Reduction of Acetals with Samarium Diiodide in Acetonitrile in the Presence of Lewis Acids
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概要
- 論文の詳細を見る
Transformation of acetals into ethers by partial reduction using a samarium diiodide-Lewis acids-acetonitrile system is described. The reaction with aromatic acetals occurred in good yields in the presence of aluminum chloride(2 eq)whereas the corresponding aliphatic, vinylic, and alkynyl derivatives did not afford ethers under the same conditions. β-Elimination to give an enol ether becomes predominant when aliphatic acetals that possess a hydrogen at the 2-position are treated with indotrimethylsilane in the presence of SmI_2 or SmI_3.
- 公益社団法人日本薬学会の論文
- 2001-01-01
著者
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Nakata Daisuke
Faculty Of Pharmaceutical Sciences And High Technology Research Center Kobe Gakuin University
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KUNISHIMA Munetaka
Faculty of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical, and Health Sciences, Kanaz
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SAKUMA Takayuki
Faculty of Pharmaceutical Sciences and High Technology Research Center, Kobe Gakuin University
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KONO Kazuhiro
Faculty of Pharmaceutical Sciences and High Technology Research Center, Kobe Gakuin University
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SATO Shoichi
Faculty of Pharmaceutical Sciences and High Technology Research Center, Kobe Gakuin University
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TANI Shohei
Faculty of Pharmaceutical Sciences and High Technology Research Center, Kobe Gakuin University
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Saito T
Faculty Of Pharmaceutical Sciences And High Technology Research Center Kobe Gakuin University
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Tani S
Faculty Of Pharmaceutical Sciences Kobe Gakuin University
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Kono K
Faculty Of Pharmaceutical Sciences And High Technology Research Center Kobe Gakuin University
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Kunishima M
Faculty Of Pharmaceutical Sciences Kobe Gakuin University:life Science Center Kobe Gakuin University
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Kunishima Munetaka
Faculty Of Pharmaceutical Sciences Institute Of Medical Pharmaceutical And Health Sciences Kanazawa
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Kunishima Munetaka
Faculty Of Pharmaceutical Sciences Kobe Gakuin University
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Sato Shoichi
Faculty Of Pharmaceutical Sciences And High Technology Research Center Kobe Gakuin University
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