Coupling Reaction of Vinyl Halides with Ketones or Aldehydes Mediated by Samarium Diiodide
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概要
- 論文の詳細を見る
The Barbier- or Grignard-type reaction of vinyl iodides with ketones or aldehydes proceeds on treatment with samarium diiodide in benzene containing hexamethylphosphoric triamide (HMPA) to afford the corresponding coupling compounds (allyl alcohols). The reaction was shown to involve vinyl samariums as an intermediate.
- 公益社団法人日本薬学会の論文
- 1999-08-15
著者
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Nakata Daisuke
Faculty Of Pharmaceutical Sciences And High Technology Research Center Kobe Gakuin University
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HIOKI Kazuhito
Faculty of Pharmaceutical Sciences, Kobe Gakuin University
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KUNISHIMA Munetaka
Faculty of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical, and Health Sciences, Kanaz
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TANI Shohei
Faculty of Pharmaceutical Sciences and High Technology Research Center, Kobe Gakuin University
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YOSHIMURA Kazuma
Faculty of Pharmaceutical Sciences, Kobe-Gakuin University
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Tani S
Faculty Of Pharmaceutical Sciences Kobe Gakuin University
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Hioki K
Faculty Of Pharmaceutical Sciences Kobe Gakuin University22:09:10life Science Center Kobe Gakuin Uni
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Hioki Kazuhito
Faculty Of Pharmaceutical Sciences Kobe Gakuin University
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Kunishima M
Faculty Of Pharmaceutical Sciences Kobe Gakuin University:life Science Center Kobe Gakuin University
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Kunishima Munetaka
Faculty Of Pharmaceutical Sciences Institute Of Medical Pharmaceutical And Health Sciences Kanazawa
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Kunishima Munetaka
Faculty Of Pharmaceutical Sciences Kobe Gakuin University
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Yoshimura K
Faculty Of Pharmaceutical Sciences Kobe-gakuin University
関連論文
- Direct Preparation of Primary Amides by Reaction of Carboxylic Acids and Ammonia in Alcohols Using DMT-MM
- Reduction of Acetals with Samarium Diiodide in Acetonitrile in the Presence of Lewis Acids
- Coupling Reaction of Vinyl Halides with Ketones or Aldehydes Mediated by Samarium Diiodide
- [2, 3]-Wittig Rearrangement Initiated by 1, 5-Hydrogen Atom Transfer from an o-Iodophenyl Group on the α-Carbon of Allylic Ethers by Reduction with SmI_2
- REDUCTION OF DITHIOACETALS WITH SmI_2 IN BENZENE-HMPA
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