Synthesis of Alkyl β-Mannosides from Mannobiose by Aspergillus niger β-Mannosidase

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概要

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• The reaction conditions for synthesis of various alkyl β-mannosides by transmannosylation with Aspergillus nibger β-mannosidase were studied. Maximum yield of methyl β-mannuoside expressed in mol% based on initial mannobiose was 81% in the presence of 50% (v/v) methanol. The longer carbon chains were, the less the yield of corresponding mannoside became. Octyl β-mannoside, a new glycoside, was successgully synthesized in a 2 mol% yield in the presence of 90% (v/v) octanol.

• 公益社団法人日本生物工学会の論文
• 1995-11-25

著者

• Kamiyama Yoshi

  Institute Of Applied Biochemistiry University Of Tsukuba

• Itoh Hirotaka

  Institute Of Applied Biochemistry University Of Tsukuba

関連論文

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• Screening for β-Mannosidases with Transmannosidation Capacity
• The Condensation Reaction of Aspergillus niger Crude β-Xylosidase Using Xylose
• Enzymatic Synthesis of Alkyl β-Xylosides from Xylobiose by Application of the Transxylosyl Reaction of Aspergillus niger β-Xylosidase (Biological Chemistry)
• Purification and Some Properties of Aspergillus pulverulentus β-Xylosidase with Transxylosylation Capacity
• Enzymatic Synthesis of Hydroquinone β-Xyloside from Xylooligosaccharides
• Transxylosylation Products of Xylobiose by β-Xylosidase-1 from Penicillium wortmanni IFO 7237(Biological Chemistry)
• A Transxylosylation Product, α-D-Xylosylisoprimeverose, Synthesized by Bacillus α-D-Xylosidase from Isoprimeverose(Biological Chemistry)
• Substrate Specificity of Bacillus α-D-Xylosidase(Biological Chemistry)
• Synthesis of Alkyl β-Mannosides from Mannobiose by Aspergillus niger β-Mannosidase

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