Enzymatic Synthesis of Alkyl β-Xylosides from Xylobiose by Application of the Transxylosyl Reaction of Aspergillus niger β-Xylosidase (Biological Chemistry)
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概要
- 論文の詳細を見る
The enzymatic synthesis of alkyl β-xylosides from xylobiose and alcohols through the transxylosyl reaction of Aspergillus niger IFO 6662 enzyme was studied. Various alkyl β-xylosides were effectively synthesized from xylobiose and water miscible alcohols such as methanol, ethanol, 1-propanol and 2-propanol. The molar ratios of the products, respective β-xylosides xylose, were approximately, 1:1, indicating a theoretical yield for the transfer reaction. Various water insoluble alcohols, such as 1-butnol, 1-pentanol, 1-hexanol, benzyl alcoholand 2-butanol, were also acted as effective acceptors for the transxylosyl reaction, where a great part of the synthesized β-xylosides was found in the insoluble alcohol layer, only xylose and a trace of xylobiose being found in the water layer. Therefore, the synthesized β-xylosides, such as 1-hexyl β-xyloside, could be readily separated from the reaction mixture and crystallized after evaporation of the insoluble alcohol.
- 社団法人日本農芸化学会の論文
- 1988-09-23
著者
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YASUI Tsuneo
Institute of Applied Biochemistry, University of Tsukuba
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Kamiyama Yoshi
Institute Of Applied Biochemistry University Of Tsukuba
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Kamiyama Yoshi
Institute Of Applied Biochemistiry University Of Tsukuba
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Yasui Tsuneo
Institute Of Applied Biochemistry Tsukuba University
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Yasui Tsuneo
Institute Of Applied Biochemistry The University Of Tsukuba
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Yasui Tsuneo
Institute Of Applied Biochemistry University Of Tsukuba:(present Address) Seitoku Junior College Of
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SHINOYAMA Hirofumi
Institute of Applied Biochemistry, University of Tsukuba
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安井 勉
Department Of Animal Science Faculty Of Agriculture Hokkaido University
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Shinoyama H
Department Of Advanced Bioresources Science Graduate School Of Science And Technology Chiba Universi
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Shinoyama Hirofumi
Institute Of Applied Biochemistry University Of Tsukuba
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