Degradative Pathway of 2-Deceno-δ-lactone by the Lactone-producing Fungus, Fusarium solani

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概要

• 論文の詳細を見る

• The degradative pathway of 5-alkanolides (alkano-δ-lactones) and 2-deceno-δ-lactone (massoialactone) by Fusarium solani PM-1, a massoialactone-producing fungus, was investigated. (±)-Alkano-δ-lactones were shown to be degraded first to a one-carbon-atom-less methyl ketone, 4-hydroxy-2-alkanones, after hydroxylation. The 4-hydroxy-2-alkanones were then converted to 2,4-alkanediones or to 2,4-alkanediols, and are suggested to be successively degraded by modified β-oxidation. (R)-Massoialactone, the main compound in the volatiles produced by the strain, was first saturated to (R)-decano-δ-lactone, and then this saturated lactone was degraded in the same way. These observations lead to a conceptional cycle of acetate moieties throughout the production and degradation of the secondary metabolites.

• 社団法人日本農芸化学会の論文
• 1993-12-23

著者

• MATSUMOTO Miwako

  Department of Bioscience, Faculty of Bioresources, Mie University

• Nago Hiroshi

  Department Of Civil Engineering Okayama University

• Nakai Syuryo

  Department of Food Science, University of British Columbia

• Matsumoto Miwako

  Department Of Bioscience Faculty Of Bioresources Mie University

• Nakai Syuryo

  Department Of Food Science University Of British Columbia

関連論文

• Purification and Characterization of the Family J Catalytic Domain Derived from the Clostridium thermocellum Endoglucanase CelJ
• Gas Chromatographic Enantiomeric Separation of 5-Alkanolides with Simple Conversion in a Column Coated with a Cyclodextrin Derivative
• An Ecological Role of Volatiles Produced by Lasiodiplodia theobromae
• 2-Deceno-δ-lactone-producing Fungi, Strains of Fusarium solani, Isolated by Using a Medium Containing Decano-δ-lactone as the Sole Carbon Source
• PORE PRESSURE AND EFFECTIVE STRESS IN A HIGHLY SATURATED SAND BED UNDER WATER PRESSURE VARIATION ON ITS SURFACE
• Degradative Pathway of 2-Deceno-δ-lactone by the Lactone-producing Fungus, Fusarium solani
• (R)-2-Octeno-δ-lactone and Other Volatiles Produced by Lasiodiplodia theobromae
• Enantiomeric Composition of 5-Alkanolides Contained in Coconut and Dairy Products
• 2'-Hydroxy-4'-methoxyacetophenone (Paeonol) in Exacum affine cv.

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