溶融Al-Mg-Si合金の指向性酸化法によるSiC繊維/Al_2O_3/Al合金ハイブリッド複合体材料の製造

概要

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Al_2O_3/Al alloy hybrid composites (SiC/Al_2O_3/Al alloy hybrid composite) reinforced with chopped and continuous SiC fiber (Nicalon^<TM>) have been fabricated by directed metal oxidation of Al-Mg-Si alloys. Effects of additive elements, Mg and Si on the in situ formation of SiC/Al_2O_3/Al alloy composites were studied. In situ infiltration of the Al_2O_3/Al alloy composite phase into the SiC fiber was possible only when a small quantity of Mg (5 mass%) was used. No infiltration was observed for 10 mass% Mg alloys. Composites fabricated from Al ・ 5Mg ・ 5Si and Al ・ 5Mg ・ 10Si alloys showed incorporation of Al_2O_3/Al alloy composite into the SiC fibers. The silicon content of the alloy affected the fabrication of the composite by altering the growth rate of the oxide, and the fastest fabrication of the composite was possible using Al ・ 5Mg ・ 5Si alloys. It was concluded that aluminum alloys of lower Mg contents ( < 5 mass% ) are recommendable as a starting aluminum alloy for the incorporation of Al_2O_3/Al alloy composite phase into the SiC fibers with void free structure. However, degradation of the fiber during incorporation should be considered the application of this process.
1996-09-01