X-Ray Studies on Successive Structural Transitions in RbLiSO_4

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概要

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• Space groups and super-lattice structures of five phases of RbLiSO. are inves-tigated by X-ray diffraction method. Phase I (7'>204'C) is paraelectric (Pmcn-D".')). The incommensurate phase IT (202<7'<204'C) is characterized by a wavenumber A.=(2TJ)/5 with J(7')=0.0l3(204'C) -0.137(202'C). Phase III takesc=2c. structure which belongs to P2./cll-C';., where c. is the cell dimensionin phase [. The ferroelectric phase IV (166<7'<l85'C) belongs to Plln-C!and takes c=5c. super-structure. The I-II transition is 2nd order and the criticalexponent is /7=0.36]0.05, while other three transitions are lst order ones.

• 社団法人日本物理学会の論文
• 1979-10-15

著者

• Shiroishi Yoshihiro

  Hitachi Central Research Laboratory

• Sawada Shozo

  Department Of Engineering Physics Chubu Institute Of Technology

• TANISAKI Sigetosi

  Faculty of Law and Economics,Yahata University

• Hasebe K

  Yamaguchi Univ. Yamaguchi

• Hasebe Katsuhiko

  Department of Physics, Biology and Informatics, Faculty of Science, Yamaguchi University

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