Homochirality Proliferation in Space(Cross-disciplinary Physics and Related Areas of Science and Technology)

概要

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To understand the chirality selection in the biological organic system, a simple lattice model of chemical reaction with molecular diffusion is proposed and studied by Monte Carlo simulations. In addition to a simple stochastic process of conversion between an achiral reactant A and chiral products, R and S molecules, a nonlinear autocatalysis is incorporated by enhancing the reaction rate from A to R (or S), when A is surrounded by more than one R (or S) molecules. With this nonlinear autocatalysis, the chiral symmetry between R and S is shown to be broken in a dense system. In a dilute solution with a chemically inactive solvent, molecular diffusion accomplishes chirality selection, provided that the initial concentration is higher than the critical value.
社団法人日本物理学会の論文
2004-07-15