Nuclear Magnetic Resonance of Transition Elements in Paramagnetic Salts
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概要
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Nuclear magnetic resonance of transition elements in paramagnetic salts under two situations is studied theoretically. One is the case where the magnetic ions have no Kramers degeneracy and their spin degeneracy is completely lifted by the combined action of the spin-orbit coupling and the crystalline electric field. Another is the case of the ideal paramagnetic substances under a strong magnetic field and at low temperatures. The resonance field (or frequency) shift, the relaxation times T_1 and T_2 due to hyperfine interaction and the indirect nuclear spin coupling via electron spins are calculated. The results show that the nuclear resonance of transition elements in paramagnetic salts is expected to be observable under favorable conditions.
- 社団法人日本物理学会の論文
- 1958-11-05
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