Spin Quenching and Magnetic Resonance
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概要
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The effect of the magnetic ions of those paramagnetic salts whose spin degeneracy is completely lifted by the combined action of the spin-orbit coupling and the crystalline electric field, on the magnetic resonance of nuclear spins and electronic spins of other kind of ions such as Cu^<2+>, Co^<2+>, Mn^<2+> substituted for the host ions are studied theoretically. General formulas for the resonance field shift, line width and the thermal relaxation time in nuclear (or electron) spin resonance in magnetic substances are given. T_1 and T_2 are here related to the difference between isothermal and isolated susceptibilities. Temperature dependence of T_1 and T_2 as well as magnetic field dependence of them are studied. At low temperatures they become longer rapidly (exponentially) as temperature is lowered while at high temperatures they are independent of temperature. Field dependence of the line width is of the type of H_0^2 + H_i^2 when the line is narrowed by spin-spin interaction among the host ion spins, or √<H_0^2 + H_i^2> when the line is not narrowed, where H_i denotes the local magnetic field. Field dependence of 1/T_1 is always like H_0^2 + H_i^2. The theoretical results are compared with some available experimental data on electron spin resonance. The agreement between theory and experiment seems to be not unreasonable as far as order of magnitude and qualitative characters of the line width are concerned, though experimental data are now rather scanty.
- 社団法人日本物理学会の論文
- 1958-11-05
著者
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Moriya Toru
Department Of Physics Faculty Of Science And Technology Science University Of Tokyo
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OBATA Yukio
Department of Physics, University of Tokyo
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Obata Yukio
Department Of Physics Faculty Of Science University Of Tokyo
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Obata Yukio
Department Of Physics University Of Tokyo
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Moriya Toru
Deparment Of Physics Wasea University
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Obata Yukio
Department of Information Science, Kanagawa University
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